Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters     

Lindsay Whalin  Eun-Hee Kim  Robert Mason 《Marine Chemistry》2007

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.  相似文献   

Circalittoral Macrobenthic Assemblages of Strymonikos Gulf (North Aegean Sea)   总被引：1，自引：0，他引：1  

Costas G.  Dounas Athanasios S.  Koukouras 《Marine Ecology》1992,13(2):85-99

Abstract. Six macrobenthic assemblages of the circalittoral zone found in Strymonikos Gulf, North Aegean Sea, are described and compared with the corresponding ones from other Mediterranean and Atlantic areas. For the delimination of these assemblages and the evaluation of the major environmental gradients governing their distribution, several numerical techniques were used.  相似文献   

泉州潮间带贝类的生态分布     

谢进金  谢进辉  林娟娟  冯琳  齐兆明  陈琳钦 《海洋科学》2006,30(1):54-62

报道了泉州市潮间带贝类的种类、数量及其生态分布。经记录整理、鉴定共得标本125种,隶属于3纲、46科和84属。其中,多板纲3种,双壳纲63种,腹足纲59种。根据它们对温度的适应性质可分为4个类群:暖温带种占5.6%;亚热带种占40.8%;广温广布种占48.0%;热带种占5.6%。  相似文献   

The Vema Transverse Ridge (Central Atlantic)     

Kastens  Kim  Bonatti  Enrico  Caress  David  Carrara  Gabriela  Dauteuil  Olivier  Frueh-Green  Gretchen  Ligi  Marco  Tartarotti  Paola 《Marine Geophysical Researches》1998,20(6):533-556

Transverse ridges are elongate reliefs running parallel and adjacent to transform/fracture zones offsetting mid-ocean ridges. A major transverse ridge runs adjacent to the Vema transform (Central Atlantic), that offsets the Mid-Atlantic Ridge by 320 km. Multibeam morphobathymetric coverage of the entire Vema Transverse ridge shows it is an elongated (300 km), narrow (<30 km at the base) relief that constitutes a topographic anomaly rising up to 4 km above the predicted thermal contraction level. Morphology and lithology suggest that the Vema Transverse ridge is an uplifted sliver of oceanic lithosphere. Topographic and lithological asymmetry indicate that the transverse ridge was formed by flexure of a lithospheric sliver, uncoupled on its northern side by the transform fault. The transverse ridge can be subdivided in segments bound by topographic discontinuities that are probably fault-controlled, suggesting some differential uplift and/or tilting of the different segments. Two of the segments are capped by shallow water carbonate platforms, that formed about 3–4 m.y. ago, at which time the crust of the transverse ridge was close to sea level. Sampling by submersible and dredging indicates that a relatively undisturbed section of oceanic lithosphere is exposed on the northern slope of the transverse ridge. Preliminary studies of mantle-derived ultramafic rocks from this section suggest temporal variations in mantle composition. An inactive fracture zone scarp (Lema fracture zone) was mapped south of the Vema Transverse ridge. Based on morphology, a fossil RTI was identified about 80 km west of the presently active RTI, suggesting that a ridge jump might have occurred about 2.2 m.a. Most probable causes for the formation of the Vema Transverse ridge are vertical motions of lithospheric slivers due to small changes in the direction of spreading of the plates bordering the Vema Fracture Zone.  相似文献   

Annual Anthropogenic Carbon Transport into the North Pacific Intermediate Water through the Kuroshio/Oyashio Interfrontal Zone: An Estimation from CFCs Distribution     

Tsuneo Ono  Yutaka W. Watanabe  Katsuyuki Sasaki 《Journal of Oceanography》2000,56(6):675-689

Vertical distribution of anthropogenic carbon content of the water (exDIC) in the Oyashio area just outside of the Kuroshio/Oyashio Interfrontal Zone (K/O Zone) was estimated by the simple 1-D advection-diffusion model calibrated by the distribution of chlorofluorocarbons (CFCs). The average concentration of exDIC for = 26.60–27.00 is multiplied by the volume transport of Oyashio water into the North Pacific Intermediate Water (NPIW) to estimate the annual transport of exDIC into NPIW through K/O Zone. The estimated transport of exDIC was 0.018–0.020 GtC/y, which corresponds to 15% of the whole total exDIC accumulation in the temperate North Pacific. A simple assessment using the NPIW 1-box model indicates that the current study explains at least 70% of the total annual transport of exDIC into NPIW, and that small exDIC sources for NPIW still exists in addition to K/O Zone.  相似文献   

威海地区高压岩石组合及其成因演化     

韩宗珠  王来明  张希道  毛振业 《中国海洋大学学报(自然科学版)》1993,(3)

利用矿物地质温压计估算变质高峰期温压条件、退变质作用温压条件。研究表明,本区为鲁苏构造带的北延部分,代表本区晚元古代华南陆块与华北陆块的碰撞及三叠纪华北陆块向华南陆块推覆事件的发生和演化。  相似文献   

福建深沪湾潮间带全新世有孔虫及其环境意义   总被引：2，自引：1，他引：2  

王绍鸿  俞鸣同  唐丽玉  赵希涛  王雪梅  黄向华 《台湾海峡》2002,21(1):6-11

本文对深沪湾西部潮间带表层沉积物和两个钻孔岩芯共30个样品的有孔虫组成进行了定性和定量分析。结果表明，表层沉积物中有孔虫群分布规律明显，随着离岸向海越远，水深越大，有孔虫娄量从1倍数上升到5位数，种数为9-69种，多变度V31-44，复合分异度H（s)3.25-3.25。从钻孔岩芯中的全新世有孔虫群特征可看出，中全新世以来海面升降和海洋环境可分为2个阶段：（1）海水初到钻孔位置，有孔虫数量和种数较少，分异度不高，海相性程度较低。（2）后期（埋深1.8m和2.0m以浅），海面有所升高，变为潮间带（高潮位→中潮位→低潮位）环境。  相似文献   

Formation of ‘Beach Rock’ at Siesta Key, Florida and its influence on barrier island development     

Darren Spurgeon  Richard A. Davis  Jr.  Eugene A. Shinnu 《Marine Geology》2003,200(1-4):19-29

Seaward-dipping strata of carbonate-cemented shell debris located along the coast of Siesta Key on the Gulf Coast of the Florida peninsula have long been interpreted to be beachrock equivalent in age to the Pleistocene Anastasia Formation (Stage 5e) of the east coast of Florida. Detailed examination of thin sections along with radiometric dating and isotopic analyses demonstrates clearly that this is a Holocene deposit that is not beachrock but was lithified in a meteoric environment. Whole rock dates, dates from shells only, and from cement only demonstrate that these beach deposits were in place by at least 1800 yr BP and might have been there as long ago as 4300 yr BP. This means that some type of barrier island was in place at that time. Previous investigations have depicted Siesta Key as having a maximum age of 3000 yr with these deposits being located about 2 km landward of the beach deposits. This suggests that the beach deposits might have been the site of the original position of Siesta Key. These data also indicate that sea level must have been near its present position at the time that these foreshore beach deposits were deposited; sometime between 1800 and 4300 yr ago. This scenario indicates that sea level along this coastal reach probably reached its present level at least about 2000 yr ago.  相似文献   

南海西部断裂系研究及其物理模拟实验证据   总被引：3，自引：1，他引：3  

孙龙涛  孙珍  詹文欢  孙宗勋  赵明辉  夏少红 《海洋学报》2006,28(3):64-71

南海西部断裂系是由四条典型的走滑断裂所组成的断裂系统,是南海扩张的西部边界.此断裂系主要是在白垩纪以来的印-藏碰撞、新生代印支挤出和南海扩张的共同作用下形成的.通过模拟实验,探讨此断裂系的成因、演化过程,认识到此断裂系经历了五期构造运动.  相似文献   

海岸带空间要素分析查询系统构建研究——以山东莱州湾为例     

黄卫民  王瑞富  张培文  张杰 《海洋科学进展》2001,19(4):81-85

海岸带开发与保护是我国保持海岸带可持续发展所急需解决的问题。以莱州湾为示范区 ,利用 GIS技术建立海岸带空间要素分析查询系统 ,旨在为实施海岸带的综合管理构建一个高技术支撑的信息分析系统  相似文献